Bending-Type Electron Donor–Donor–Acceptor Triad: Dual Excited-State Charge-Transfer Coupled Structural Relaxation
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.9b02712
Abstract: The triad types of molecules with various combinations of electron donors (D) and acceptors (A) have been widely explored in optoelectronics. However, their photophysical and photochemical properties, which are frequently unconventional, are relatively unexplored. In… read more here.
Keywords: donor donor; donor acceptor; donor; acceptor ... See more keywords
Palladium-catalyzed intramolecular enantioselective C(sp3)–H insertion of donor/donor carbenes
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc03524c
Abstract: Herein, the first palladium-catalyzed intramolecular enantioselective C(sp3)–H insertion reaction of donor–donor carbenes has been successfully achieved. This facile protocol enables the rapid construction of a collection of enantioenriched decorated indolines with two contiguous stereocenters in… read more here.
Keywords: donor donor; catalyzed intramolecular; palladium catalyzed; intramolecular enantioselective ... See more keywords