Adducts of Donor-Functionalized Ar3P with the Soft Lewis Acid I2: Probing Simultaneous Lewis Acidity and Basicity at Internally Solvated P(III) Centers.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00278
Abstract: The enhancement of donor strength of ortho-functionalized triarylphosphanes is shown to occur via different mechanisms for O- and N-donor substituents, with internal solvation of the phosphorus center observed for N donors. Nevertheless, the steric congestion… read more here.
Keywords: donor; donor functionalized; lewis acid; internal solvation ... See more keywords
Bidentate Donor-Functionalized N-Heterocyclic Carbenes: Valuable Ligands for Ruthenium-Catalyzed Transfer Hydrogenation
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DOI: 10.3390/molecules27154703
Abstract: Ruthenium complexes are by far the most studied compounds that catalyze hydrogen transfer reactions. In this review, we describe the use in this field of ruthenium complexes bearing bidentate donor-functionalized N-heterocyclic carbene ligands. The review… read more here.
Keywords: donor functionalized; functionalized heterocyclic; transfer hydrogenation; transfer ... See more keywords