Delineating factors that dictate the framework of a bulky phosphate derived metal complexes: Sterics of phosphate, anion of the metal salt and auxiliary N-donor ligand
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.08.033
Abstract: Abstract A bulky phosphate, 2,6-dibenzhydryl-4-methylphenyl dihydrogen phosphate ( L 1 H 2 ) is synthesized from the reaction of 2,6-dibenzhydryl-4-methylphenol with POCl 3 followed by hydrolysis. L 1 H 2 reacts with metal nitrates, M(NO… read more here.
Keywords: donor ligand; ligand; anion metal; phosphate ... See more keywords
Design, synthesis, characterization and photoluminescence studies of two new coordination polymers based on 4,4′-oxybis(benzoic acid) and N-donor ligand with transition metals
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.06.093
Abstract: Abstract Two novel one dimensional coordination polymers of cobalt and copper with 4,4′-oxybis(benzoic acid) (H2OBA) and N-donor ligand-1H-imidazole (IM), [Co(OBA)(IM)2(H2O)]n (1) and {[Cu2(OBA)2(IM)3(H2O)2]·5H2O}n (2) have been prepared by single gel diffusion technique at ambient condition… read more here.
Keywords: donor ligand; coordination; oxybis benzoic; photoluminescence studies ... See more keywords
First Report on the Separation of Trivalent Lanthanides from Trivalent Actinides Using an Aqueous Soluble Multiple N-Donor Ligand, 2,6-bis(1 H-tetrazol-5-yl)pyridine: Extraction, Spectroscopic, Structural, and Computational Studies.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00142
Abstract: A terdentate multiple N donor ligand, 2,6-bis(1 H-tetrazol-5-yl)pyridine (H2BTzP), was synthesized, and its complexation with trivalent americium, neodymium, and europium was studied using single-crystal X-ray diffraction, attenuated total reflectance-fourrier transform infrared spectroscopy, time-resolved fluorescence spectroscopy,… read more here.
Keywords: donor ligand; multiple donor; ligand bis; tetrazol pyridine ... See more keywords
A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04555g
Abstract: A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(iii) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic analysis revealed unique properties which… read more here.
Keywords: donor ligand; mesoionic nitrogen; nitrogen donor; iridium ... See more keywords
A 2D layer network assembled from an open dendritic silver cluster Cl@Ag11N24 and an N-donor ligand
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/c9qi01100e
Abstract: A 2D layer network was synthesized from an N-donor ligand and a new silver cluster featuring an open dendritic structure with a high coordination ratio of N atom. Both the assembly process and luminescence properties… read more here.
Keywords: donor ligand; layer network; open dendritic; silver cluster ... See more keywords
PtII(C^N)(N-donor ligand)Cl-type complexes showing highly sensitive aggregation-induced phosphorescent emission (AIPE) behavior fulfilled by long-size ligands and distorted molecular configuration
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt00238a
Abstract: A series of four-coordinated PtII(C^N)(N-donor ligand)Cl-type complexes have been synthesized through combination between long-size C^N-type and N-donor ligands. In addition, by variating the coordinating site in the N-donor ligand, distorted... read more here.
Keywords: type complexes; ptii donor; ligand; donor ligand ... See more keywords
Heterometallic Cu(II)-M(II) (M = Mg, Ca and Sr) complexes with a N,O-donor ligand in situ generated from topiroxostat
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1734189
Abstract: Abstract By introducing alkaline-earth metal ions (Mg2+, Ca2+, and Sr2+) as structure-directing agents, three new heterometallic complexes, Mg(H2O)6·[Cu2Mg(L)4(H2O)4]·4H2O (1), [CuCa(L)2(H2O)4]n (2) and [CuSr(L)2(H2O)4]n (3) [H2L = 4-(3-(pyridine-4-yl)-1H-1,2,4-triazol-5-yl)picolinic acid], have been synthesized under hydrothermal conditions and… read more here.
Keywords: donor ligand; heterometallic complexes; situ generated; h2o ... See more keywords
Opportunities and challenges of applying advanced X-ray spectroscopy to actinide and lanthanide N-donor ligand systems
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Synchrotron Radiation"
DOI: 10.1107/s1600577521012091
Abstract: Exploring the opportunities and challenges when studying actinide and lanthanide N-donor ligand systems relevant for separation technologies from the metal and ligand point of view using X-ray spectroscopy techniques and computations. read more here.
Keywords: spectroscopy; lanthanide donor; opportunities challenges; actinide lanthanide ... See more keywords