Adaptable ligand donor strength: tracking transannular bond interactions in tris(2-pyridylmethyl)-azaphosphatrane (TPAP).
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03180k
Abstract: Flexible ligands that can adapt their donor strength have enabled unique reactivity in a wide range of inorganic complexes. Most examples are composed of flexible multi-dentate ligands containing a donor that can vary its interaction… read more here.
Keywords: strength; adaptable ligand; azaphosphatrane tpap; tris pyridylmethyl ... See more keywords
Electrostatic vs. inductive effects in phosphine ligand donor properties and reactivity
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DOI: 10.1039/d1sc04277g
Abstract: Enhanced rates and selectivity in enzymes are enabled in part by precisely tuned electric fields within active sites. Analogously, the use of charged groups to leverage electrostatics in molecular systems is a promising strategy to… read more here.
Keywords: inductive effects; donor; electrostatic inductive; donor strength ... See more keywords