From classical to supramolecular dynamic stereochemistry: Double crystallization-induced diastereomerization of thiazine sulfonamide.
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DOI: 10.1002/chir.23316
Abstract: The interrelation between the configurational lability of nitrogen and sulfur atoms within the -NH-SO2 group of some thiazine sulfonamides is discussed. We have found that the compounds of the above series can crystallize as various… read more here.
Keywords: induced diastereomerization; double crystallization; crystallization induced; thiazine ... See more keywords