Synthesis, Structures, and Reactivity of Single and Double Cyclometalated Complexes Formed by Reactions of [Cp*MCl2]2 (M = Ir and Rh) with Dinaphthyl Phosphines
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DOI: 10.1021/acsomega.8b00193
Abstract: Reactions of two dinaphthyl phosphines with [Cp*IrCl2]2 have been carried out. In the case of di(α-naphthyl)phenylphosphine (1a), a simple P-coordinated neutral adduct 2a is obtained. However, tert-butyldi(α-naphthyl)phenylphosphine (1b) is cyclometalated to form [Cp*IrCl(P^C)] (3b). Complexes… read more here.
Keywords: synthesis structures; structures reactivity; cyclometalated complexes; double cyclometalated ... See more keywords