Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc02910j
Abstract: Combination of phosphoryl and calix[4]arene moieties in the same organic framework (LPO) directs the formation of homoleptic double-decker complexes [LnIII(LPO)2](OTf)3 for Ln = Tb and Dy, with the latter displaying slow relaxation of the magnetisation. read more here.
Keywords: calix arene; phosphorylated calix; deckers single; arene double ... See more keywords
Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00769j
Abstract: Complementarity of calixarene (H2L) and polyoxometalate ligands results in the first organic-inorganic [MIIIL{Mo5O13(OMe)4(NO)}]2- (M = Y, Gd and Dy) hybrid, directing the formation of a distorted square-antiprismatic MO8 ligand field and resulting in slow relaxation… read more here.
Keywords: deckers based; based calixarene; lanthanide double; double deckers ... See more keywords