Uncovering pseudo-doublet ground states innate to U(IV) complexes through magnetism
Sign Up to like & getrecommendations! Published in 2021 at "Chem"
DOI: 10.1016/j.chempr.2021.06.015
Abstract: In the June issue of Chem, Chilton, Liddle, and colleagues reported the synthesis and characterization of uranium(IV)-oxo and -imido complexes that exhibit anomalously high low-temperature magnetic moments as a result of nearly doubly degenerate spin-orbit… read more here.
Keywords: uncovering pseudo; ground; ground states; doublet ground ... See more keywords
Doublet Ground State in a Vanadium(II) Complex: Redox and Coordinative Noninnocence of Tripodal Ligand Architecture.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03418
Abstract: We report on the geometric and electronic structures of a series of V2+/3+ tren-bridged iminopyridine complexes [tren = tris(2-aminoethyl)amine] that enable the observation of an unexpected doublet ground state for a nominally 3d3 species. Tren… read more here.
Keywords: ground state; doublet ground; ligand;