Active Response of Six-Coordinate Cu2+ on CO2 Uptake in Cu(dpa)2SiF6-i from in Situ X-ray Absorption Spectroscopy
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DOI: 10.1021/acs.jpcc.7b02623
Abstract: Interpenetrated metal organic framework (MOF) Cu(dpa)2SiF6-i (dpa = dipyridyl acetylene) with 6-coordinate copper takes up CO2 with isosteric heat of sorption Qst ≅ 40 kJ/mol, comparable to MOFs designed to have specific, strong chemisorption interactions.… read more here.
Keywords: ray absorption; absorption spectroscopy; dpa 2sif6; situ ray ... See more keywords