A decanuclear Pt complex comprised of an unbridged Pt4 chain capped by two Pt3 A-frame units supported by meso-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2
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DOI: 10.1016/j.jorganchem.2019.01.010
Abstract: Abstract A linear tetraphosphine meso-bis[(diphenylphosphinomethyl)phenylphosphino]methane (meso-dpmppm), was utilized to prepare a PtI dinuclear complex, [Pt2(μ−meso-dpmppm−κ2,κ1)(XylNC)3](PF6)2 (2), which was derived from reaction of [PtII(meso-dpmppm−κ3)(XylNC)](PF6)2 (1) with 1/3 equiv. of [Pt3(XylNC)6]. Treatment of 2 with 1/3 equiv.… read more here.
Keywords: pt3; dpmppm xylnc; xylnc; meso dpmppm ... See more keywords