Transforming PPh3 into bidentate phosphine ligands at Ru-Zn heterobimetallic complexes.
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DOI: 10.1039/c9dt03106e
Abstract: The reaction of [Ru(PPh3)3Cl2] with excess ZnMe2 led to P-C/C-H bond activation and P-C/C-C bond formation to generate a chelating diphenylphosphinobenzene ligand as well as a cyclometallated (diphenylphosphino)biphenyl group in the final product of the… read more here.
Keywords: pph3; bond; dppbz; biphenyl ... See more keywords