Preparation and Characterization of the Triflate Complex [Cp*(dppe)FeOSO2 CF3 ]: A Convenient Access to Labile Five- and Six-Coordinate Iron(I) and Iron(II) Complexes
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DOI: 10.1002/ejic.201901086
Abstract: Treatment of the iron hydride [Cp*(dppe)FeH] (1) with methyl triflate (CH3OSO2CF3) yielded the iron triflate adduct [Cp*(dppe)FeOSO2CF3] (4, 85 %). In the solid state, the triflate is coordinated at the iron center as shown by… read more here.
Keywords: triflate; dppe; complex dppe; iron ... See more keywords