Reversible Small‐Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters
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DOI: 10.1002/ejic.201700539
Abstract: [8,8-(dppe)-nido-8,7-NiSB9H11] 1, [7-Et-8,8-(dppe)-nido-8,7-NiSB9H10] 2, [9-Et-8,8-(dppe)-nido-8,7-NiSB9H10] 3, and [2,2-(dppe)-closo-2,1-NiSB8H8] 4, are isolated from the reaction between Cs[arachno-SB9H12], Li[BHEt3] and [NiCl2(dppe)] at low temperature in yields of 30%, 1%, 0.1% and < 1%, respectively. The arachno-nickellathiadecaborane [6,6-(dppe)-arachno-6,9-NiSB8H10]… read more here.
Keywords: molecule; dppe; nido; metal ... See more keywords