[Au18(dppm)6Cl4]4+: a phosphine-protected gold nanocluster with rich charge states.
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DOI: 10.1039/c9dt00042a
Abstract: A diphosphine-protected 18-gold-atom nanocluster was isolated via a facile reduction of an AuI precursor by NaBH4. Its composition was identified as {[Au18(dppm)6Cl4]·C6H6·3Cl·PF6} (SD/Au18, SD = SunDi; dppm = bis-(diphenylphosphino)methane) by X-ray single crystal structural analysis.… read more here.
Keywords: dppm 6cl4; au18 dppm; protected gold; nanocluster ... See more keywords