Assembly, structures, electrocatalytic and photocatalytic properties of a series of Anderson-type polyoxometalate-based metal–organic complexes based on flexible pyridyl-amide ligands
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DOI: 10.1016/j.poly.2016.12.040
Abstract: Abstract Five new Anderson-type polyoxometalate-based metal–organic complexes, [Cu4(μ3-OH)2(H2O)6(4-dpye)2(TeMo6O24)]·2H2O (1), [Cu(4-dpyb)(CrMo6(OH)6O18)2(H2O)2][Cu(4-dpyb)(H2O)4](4-H2dpyb)·6H2O (2), H[Cu2(3-dpyb)2(C2O4)(CrMo6(OH)6O18)]·8H2O (3), [Cu2(4-dpyh)(CrMo6(OH)5O19)(H2O)8]·10H2O (4) and [Cu4(μ2-OH)(μ3-OH)(H2O)6(4-dpyh)(TeMo6O24)]·H2O (5) (4-dpye = N,N′-bis(4-pyridinecarboxamide)-1,2-ethane, 4-dpyb = N,N′-bis(4-pyridinecarboxamide)-1,4-butane, 3-dpyb = N,N′-bis(3-pyridinecarboxamide)-1,4-butane, 4-dpyh = N,N′-bis(4-pyridinecarboxamide)-1,6-hexane), were hydrothermally prepared and structurally characterized by single crystal X-ray diffraction analyses and… read more here.
Keywords: type polyoxometalate; anderson type; h2o; dpyb ... See more keywords