Light-Driven Carbon-Carbon Coupling of α-sp3-CH of Aliphatic Alcohols with sp2-CH Bond of 1,4-Naphthoquinones.
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DOI: 10.1021/acs.orglett.2c03066
Abstract: Here, an α-selective Csp3-H bond functionalization of primary aliphatic alcohols with 1,4-naphthoquinones yielded Csp2-Csp2 coupled products driven by blue-LED light under catalyst, metal, base, and reagent-free conditions. In this transformation, cleavage of three C-H bonds… read more here.
Keywords: driven carbon; carbon; aliphatic alcohols; carbon carbon ... See more keywords