Reversible Redox‐Driven Crystallization in a Paracyclophane Monolayer at a Solid–Liquid Interface
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202315861
Abstract: The development and integration of cyclophanes into future functional materials require a detailed understanding of the physicochemical principles that underlie their properties, phase behavior, and in particular the relationship between structure and function. Here, electrochemically… read more here.
Keywords: redox driven; crystallization paracyclophane; crystallization; driven crystallization ... See more keywords
Stereochemical switch driven by crystallization: Interplay between stoichiometry and configuration of the products.
Sign Up to like & getrecommendations! Published in 2022 at "Chirality"
DOI: 10.1002/chir.23451
Abstract: An intriguing example of a crystallization-induced stereochemical switch in the configuration of aza-Michael reaction products is described. Depending on both the stereochemical purity and stoichiometric ratio of the chiral amine used, the reaction delivers crystalline… read more here.
Keywords: switch driven; stereochemical switch; crystallization; configuration ... See more keywords
Entropy-Driven Crystallization of Hard Colloidal Mixtures of Polymers and Monomers
Sign Up to like & getrecommendations! Published in 2024 at "Polymers"
DOI: 10.3390/polym16162311
Abstract: The most trivial example of self-assembly is the entropy-driven crystallization of hard spheres. Past works have established the similarities and differences in the phase behavior of monomers and chains made of hard spheres. Inspired by… read more here.
Keywords: hard colloidal; crystallization; crystallization hard; driven crystallization ... See more keywords