Visible-Light-Driven Decarboxylative Alkylation of C-H Bond Catalyzed by Dye-Sensitized Semiconductor.
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DOI: 10.1021/acs.orglett.8b01077
Abstract: A decarboxylative alkylation of benzylic C(sp3)-H bonds of N-aryl tetrahydroisoquinolines under the irradiation of blue light is reported, featuring a broad substrate scope, low cost, heavy-metal-free, and mild conditions. A preliminary mechanistic study indicated that… read more here.
Keywords: alkylation bond; decarboxylative alkylation; visible light; driven decarboxylative ... See more keywords