Assemblies of Increasingly Large Ln-Containing Polyoxoniobates and Intermolecular Aggregation-Disaggregation Interconversions.
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DOI: 10.1021/jacs.2c09546
Abstract: An oxalate-assisted lanthanide (Ln) incorporation strategy is first demonstrated for creating rare high-nuclearity Ln-containing polyoxoniobates (PONbs). With the strategy, a series of high-nuclearity Ln-containing PONbs of 50-nuclearity Dy2Nb48, 103-nuclearity Dy7Nb96, 200-nuclearity Dy10Nb190, and 206-nuclearity Dy14Nb192… read more here.
Keywords: nuclearity; containing polyoxoniobates; aggregation disaggregation; dy10nb190 ... See more keywords