Di- and octa-nuclear dysprosium clusters derived from pyridyl-triazole based ligand: {Dy2} showing single molecule magnetic behaviour.
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DOI: 10.1039/c7dt00047b
Abstract: Two dysprosium aggregates, formulated as [Dy2(μ-OH)2(H2bpte)2Cl2(MeOH)2]Cl2 (1), and [Dy8(μ-OH)8(bpte)8]·24H2O (2) (H2bpte = 1,2-bis(3-(pyridin-2-yl)-1H-1,2,4-triazol-5-yl)ethane), were obtained using solvothermal reactions. Upon changing the metal salt and synthetic reaction conditions, an eight-member {Dy8} (2) ring was isolated. Complex… read more here.
Keywords: single molecule; octa nuclear; dy2; dysprosium ... See more keywords
Modulating the magnetization dynamics of four phenoxo-O bridged Dy2 complexes based on a Schiff base derived from 8-hydroxyquinoline
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DOI: 10.1039/c8nj02888e
Abstract: Four novel μ-O bridged dinuclear Dy2 clusters have been synthesized successfully by utilizing an 8-hydroxyquinoline (8-HQ) Schiff base ligand and four different co-ligands: [Dy2(bfa)2(L)2(H2O)2]·4CH3OH (1), [Dy2(TTA)2(L)2(H2O)2]·4CH3OH (2), [Dy2(acac)2(L)2(H2O)2]·2H2O (3) and [Dy2(PhCOO)2(L)2(H2O)2] (4) (Hbfa = benzoyl… read more here.
Keywords: magnetization dynamics; dy2; dy2 complexes; modulating magnetization ... See more keywords
A single-ion magnet building block strategy toward Dy2 single-molecule magnets with enhanced magnetic performance.
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DOI: 10.1039/d2dt03046b
Abstract: A molecular dysprosium(III) complex [Dy(DClQ)3(H2O)2] (1) was used as a building unit for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy(III) complexes, namely [Dy2(DClQ)6(MeOH)2] (2) and [Dy2(DClQ)6(bpmo)2]·6MeCN (3) (DClQ =… read more here.
Keywords: building; ion magnet; dy2; single ion ... See more keywords
Interplay between anisotropy and magnetic exchange to modulate the magnetic relaxation behaviours of phenoxo bridged Dy2 dimers with axial β-diketonate co-ligands.
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DOI: 10.1039/d2dt03117e
Abstract: A series of Schiff base LH ((E)-2-((pyridin-2-ylmethylene)amino)phenol) supported phenoxo bridged symmetric [Dy2(L)2(hfac)4] (1), [Dy2(L)2(tfac)4] (2) and asymmetric [Dy2(L)2(thd)3(NO3)]·1.5H2O (3) binuclear complexes were isolated using differently substituted β-diketonate co-ligands (Hhfac = hexafluoroacetylacetonate, Htfac = trifluoroacetylacetonate, and… read more here.
Keywords: phenoxo bridged; dy2; magnetic exchange; diketonate ligands ... See more keywords
Metabolomics approach used for understanding temperature-related pectinase activity in Bacillus licheniformis DY2
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DOI: 10.1093/femsle/fny255
Abstract: Pectinases are enzymes that catalyze pectin degradation. There is a global demand for pectinases because of their wide utility and catalytic efficiency. Optimization of the fermentation process to increase the pectolytic enzyme activity is generally… read more here.
Keywords: temperature; dy2; tca cycle; pectinase activity ... See more keywords