Cation-Directed Synthetic Strategy Using 4f Tungstoantimonates as Nonlacunary Precursors for the Generation of 3d–4f Clusters
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DOI: 10.1021/acs.inorgchem.0c00890
Abstract: The first synthetic pathway using a series of four nonlacunary 4f-heterometal-substituted polyoxotungstate clusters Na21[(Ln(H2O)(OH)2(CH3COO))3(WO4)(SbW9O33)3]·nH2O (NaLnSbW9; Ln = TbIII, DyIII, HoIII, ErIII, YIII) as precursors for the directed preparation of nine new 3d–4f heterometallic tungstoantimonates K5Na12H3[TM(H2O)Ln3(H2O)5(W3O11)(SbW9O33)3]·nH2O… read more here.
Keywords: tbiii dyiii; hoiii eriii; eriii yiii; spectroscopy ... See more keywords
Synthesis, crystal structures and magnetic properties of a series of chair-like heterometallic [Fe4Ln2] (Ln = GdIII, DyIII, HoIII, and ErIII) complexes with mixed organic ligands.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02638j
Abstract: Four chair-like hexanuclear Fe-Ln complexes containing mixed organic ligands, namely, [Fe4Ln2{(py)2CO2}4(pdm)2(NO3)2(H2O)2Cl4]·xCH3CN·yH2O (Ln = GdIII (1, x = 1, y = 0), DyIII (2, x = 1, y = 1), HoIII (3, x = 0, y… read more here.
Keywords: gdiii dyiii; mixed organic; dyiii; chair like ... See more keywords