Intramolecular Agostic Interactions and Dynamics of a Methyl Group at a Preorganized Dinickel(II) Site
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DOI: 10.1021/acs.inorgchem.4c04255
Abstract: Alkyl nickel intermediates relevant to catalytic processes often feature agostic stabilization, but relatively little is known about the situation in oligonickel systems. The dinickel(I) complex K[LNiI2], which is based on a compartmental pyrazolato-bridged ligand L3–… read more here.
Keywords: interactions dynamics; intramolecular agostic; group; dynamics methyl ... See more keywords