Modulation of the magnetic dynamics of pentagonal-bipyramidal Co(II) complexes by fine-tuning the coordination microenvironment.
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DOI: 10.1039/d2dt02345h
Abstract: Four air-stable mononuclear Co(II) complexes, with the formulas [Co(dapbh)(H2O)(CH3OH)] (1), [Co(Hdapbh)(N3)(CH3OH)]·(CH3OH) (2), [Co(H2aapbh)(CH3OH)2]·(NO3)2 (3) and [Co(H2bapbh)(H2O)(NO3)]·(NO3) (4), have been synthesized and structurally characterized by single crystal X-ray diffraction. In all of the complexes, the Co(II)… read more here.
Keywords: magnetic dynamics; dynamics pentagonal; pentagonal bipyramidal; ch3oh ... See more keywords