Hemiporphyrazine-Involved Sandwich Dysprosium Double-Decker Single-Ion Magnets.
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DOI: 10.1021/acs.inorgchem.8b02068
Abstract: Both heteroleptic (phthalocyaninato)(hemiporphyrazinato) and homoleptic bis(hemiporphyrazinato) dysprosium double-decker complexes, Dy[H(Hp)2] (1) and Dy[H(Pc)(Hp)] (2) (H2Pc = metal-free phthalocyanine; H2Hp = metal-free hemiporphyrazine), were designed, synthesized, and structurally characterized. The dysprosium center in both double-deckers are… read more here.
Keywords: single ion; geometry; double decker; dysprosium ... See more keywords