Bis‐Alkoxide Dysprosium(III) Crown Ether Complexes Exhibit Tunable Air Stability and Record Energy Barrier
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202308548
Abstract: High‐performance and air‐stable single‐molecule magnets (SMMs) can offer great convenience for the fabrication of information storage devices. However, the controversial requisition of high stability and magnetic axiality is hard to balance for lanthanide‐based SMMs. Here,… read more here.
Keywords: stability; dysprosium iii; air; crown ether ... See more keywords
rhOver: Determination of magnetic anisotropy and related properties for dysprosium(III) single‐ion magnets by semiempirical approaches utilizing Hartree–Fock wave functions
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.25565
Abstract: Dysprosium(III) ions are promising candidates for the design of single‐ion magnets (SIMs) as they show an intrinsic strong magnetic anisotropy. However, time‐demanding multireference methods are usually necessary to reproduce low‐lying magnetic states. In this work,… read more here.
Keywords: single ion; magnetic anisotropy; dysprosium iii; anisotropy ... See more keywords
Two-dimensional dysprosium(III) coordination polymer: Structure, single-molecule magnetic behavior, proton conduction, and luminescence
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.974914
Abstract: A new dysprosium (III) coordination polymer [Dy(Hm-dobdc) (H2O)2]·H2O (Dy-CP), was hydrothermal synthesized based on 4,6-dioxido-1,3-benzenedicarboxylate (H4m-dobdc) ligand containing carboxyl and phenolic hydroxyl groups. The Dy(III) center adopts an octa-coordinated [DyO8] geometry, which can be described… read more here.
Keywords: dysprosium iii; iii coordination; luminescence; coordination polymer ... See more keywords