Enhanced performance for early transition metal nitrides via pseudocapacitance in protic ionic liquid electrolytes
Sign Up to like & getrecommendations! Published in 2017 at "Electrochemistry Communications"
DOI: 10.1016/j.elecom.2017.02.001
Abstract: Abstract Early transition metal nitrides achieve high capacitances via a pseudocapacitive mechanism that involves redox reactions with protons at their surfaces. Typically aqueous electrolytes are the source of protons, therefore the operating voltages are limited… read more here.
Keywords: ionic liquid; transition metal; early transition; protic ionic ... See more keywords
Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp2(MeCN)Ti(η1-Ge9{Si(TMS)3}3)] and K3[Cp2Ti(η1-Ge9{Si(TMS)3}2)2].
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02158
Abstract: Anionic clusters with a homoatomic [Ge9] core are species with Ge atoms in low oxidation states. In this study their reaction with early-transition-metal complexes was investigated. We report the syntheses of Ti(III) complexes of silylated… read more here.
Keywords: ge9 tms; transition metal; early transition; ge9 ... See more keywords
Composition-defined nanosized assemblies that contain heterometallic early 4d/5d-transition-metals.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03094h
Abstract: The controlled assembly of early transition metals remains a challenging research target, especially with respect to the generation of heterometallic molecules and nanomaterials. In this study, metal chlorides of the early 4d/5d-transition-metals, i.e., ZrCl4, NbCl5,… read more here.
Keywords: transition metals; composition defined; heterometallic early; early transition ... See more keywords
Hydrides of early transition metals as catalysts and grain growth inhibitors for enhanced reversible hydrogen storage in nanostructured magnesium
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta05440e
Abstract: Different contributions to the gravimetric capacity of MgH2–ETMHx nanocomposites are presented. TiH2 is the best catalyst for reversible Mg hydrogenation. read more here.
Keywords: hydrides early; catalysts grain; early transition; metals catalysts ... See more keywords
Estimation of Shear Modulus and Hardness of High-Entropy Alloys Made from Early Transition Metals Based on Bonding Parameters
Sign Up to like & getrecommendations! Published in 2023 at "Materials"
DOI: 10.3390/ma16062311
Abstract: The relationship between the tendencies towards rigidity (measured by shear modulus, G) and hardness (measured by Vickers hardness, HV) of early transition metal (ETM)-based refractory high-entropy alloys (RHEA) and bond parameters (i.e., valence electron concentration… read more here.
Keywords: modulus hardness; shear modulus; entropy alloys; early transition ... See more keywords