The Combination of Structure Prediction and Experiment for the Exploration of Alkali‐Earth Metal‐Contained Chalcopyrite‐Like IR Nonlinear Optical Material
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202106120
Abstract: Design and fabrication of new infrared (IR) nonlinear optical (NLO) materials with balanced properties are urgently needed since commercial chalcopyrite‐like (CL) NLO crystals are suffering from their intrinsic drawbacks. Herein, the first defect‐CL (DCL) alkali‐earth… read more here.
Keywords: structure; nonlinear optical; earth metal; alkali earth ... See more keywords
Ammonia Synthesis via an Associative Mechanism on Alkali Earth Metal Sites of Ca3CrN3H.
Sign Up to like & getrecommendations! Published in 2023 at "ChemSusChem"
DOI: 10.1002/cssc.202300234
Abstract: Typically, transition metals are considered as the centers for the activation of dinitrogen. Here we demonstrate that the nitride hydride compound Ca3CrN3H, with robust ammonia synthesis activity, can activate dinitrogen through active sites where calcium… read more here.
Keywords: associative mechanism; ammonia synthesis; synthesis; earth metal ... See more keywords
Anti-tumor effect of synthetic baicalin-rare earth metal complex drugs on SMMC-7721 cells
Sign Up to like & getrecommendations! Published in 2020 at "Environmental Geochemistry and Health"
DOI: 10.1007/s10653-020-00630-2
Abstract: Abstract Baicalin (BC)-rare earth metal complexes [BMCs (BC-Ce, BC-La, and BC-Y)] were synthesized by a complexation coordination method. A mouse tumor model with SMMC-7721 cells was used to examine BMCs for their anti-tumor activities in… read more here.
Keywords: earth metal; baicalin rare; rare earth; anti tumor ... See more keywords
First-Principles Study of Lattice Dynamics and Thermal Properties of Alkaline-Earth Metal Nitrides CaN, SrN, and BaN
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Superconductivity and Novel Magnetism"
DOI: 10.1007/s10948-017-4007-7
Abstract: We have performed first-principles calculations to investigate the structural, electronic, magnetic, lattice dynamics, and thermodynamic properties of ferromagnetic alkaline earth metal nitrides CaN, SrN, and BaN in the rocksalt structure using the plane-wave pseudopotential approach… read more here.
Keywords: earth metal; lattice dynamics; nitrides srn; metal nitrides ... See more keywords
Experiments on the magnetic enrichment of rare-earth metal ions in aqueous solutions in a microflow device
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Flow Chemistry"
DOI: 10.1007/s41981-019-00039-8
Abstract: An attempt is made to achieve a continuous enrichment of rare-earth metal ions from aqueous solutions in a microflow device by applying magnetic forcing. An aqueous solution containing holmium(III) ions is pumped through a small… read more here.
Keywords: earth metal; metal ions; rare earth; aqueous solutions ... See more keywords
Some Novel Rare Earth Metal Ions complexes: Synthesis, Characterization, Luminescence and Biocidal Efficiency.
Sign Up to like & getrecommendations! Published in 2020 at "Analytical biochemistry"
DOI: 10.1016/j.ab.2020.113645
Abstract: New lanthanide complexes (1-3) of the general formulae [Ln(L)(NO3)(H2O)] have been synthesized by reaction of Ln(NO3)3.xH2O {Ln = La (1), Sm (2) and Yb (3)} with 2,2'-(((1E,1'E)-thiophene-2,5-diylbis(methaneylylidene))bis(azaneylylidene))diphenol (H2L). Based on elemental analysis and spectroscopic analysis… read more here.
Keywords: earth metal; complexes synthesis; metal ions; novel rare ... See more keywords
Alkaline earth metal based single atom catalyst for the highly durable oxygen reduction reaction
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DOI: 10.1016/j.apmt.2020.100846
Abstract: Abstract Developing nonprecious group single-atom catalyst (SACs) based on alkaline earth metal has been rarely explored. Mg metal hampered the catalytic activity towards ORR due to the strong bonding of active centers with oxygenated group… read more here.
Keywords: methodology; metal; catalyst; earth metal ... See more keywords
Cationic rare-earth metal hydrides
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DOI: 10.1016/j.ccr.2016.09.009
Abstract: Abstract A survey of the literature on cationic rare-earth metal hydride complexes is presented. This overview follows systematics based on the nature of supporting ligands and provides comparisons between neutral and cationic hydrides with respect… read more here.
Keywords: metal hydrides; rare earth; cationic rare; earth metal ... See more keywords
Rare-earth metal complexes of β-diketiminato ligands bearing pendant nitrogen or oxygen donors
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DOI: 10.1016/j.ccr.2016.12.007
Abstract: Abstract By using the β -diketiminato ligands bearing pendant nitrogen or oxygen donors, a series of rare-earth metal complexes containing reactive metal-bound functionalities have been synthesized. The most notable is the synthesis of subvalent scandium… read more here.
Keywords: ligands bearing; earth metal; diketiminato ligands; rare earth ... See more keywords
Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters
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DOI: 10.1016/j.ccr.2019.04.013
Abstract: Abstract This review is focused on recent advances in the ring-opening polymerization of lactide and lactones (mainly caprolactone and β-butyrolactone) which were achieved due to the application of the initiating systems based on rare-earth complexes. read more here.
Keywords: earth metal; metal complexes; opening polymerization; rare earth ... See more keywords
Rare-earth metal–organic frameworks as advanced catalytic platforms for organic synthesis
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DOI: 10.1016/j.ccr.2020.213543
Abstract: Abstract Metal–organic frameworks (MOFs) have emerged as a new class of crystalline porous hybrid functional materials. The exceptional features of MOFs include their ultrahigh porosity, confined pore structures, configurations of active sites obtained by either… read more here.
Keywords: earth metal; rare earth; chemistry; metal organic ... See more keywords