Photoinduced Single Electron Transfer via EDA Complexation Enables Decarbonylative C(sp2)-S Bond Formation.
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DOI: 10.1021/acs.orglett.4c03910
Abstract: We have developed a photoinduced transition-metal-free decarbonylative strategy at ambient temperature through non-covalent interactions to achieve vinyl sulfones. Traditionally, decarbonylative functionalization is accomplished using transition metal catalysts at elevated temperatures. The π-π interaction facilitates the… read more here.
Keywords: transfer via; electron transfer; photoinduced single; eda complexation ... See more keywords