Visible-Light-Mediated Metal/Base-Free Stereoselective C-Alkyl Glycosylation via EDA Complexes of Glycosyl Xanthates and NHC-Borane.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c00957
Abstract: Owing to the toxic reagent and high temperature required, the application of xanthate-based radical chemistry has been limited. To address these challenges, we report a metal- and base-free, photoinduced strategy for stereoselective C-alkyl glycosylation via… read more here.
Keywords: eda complexes; alkyl glycosylation; metal base; eda ... See more keywords
A General Platform for Visible Light Sulfonylation Reactions Enabled by Catalytic Triarylamine EDA Complexes.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c11225
Abstract: Catalytic electron donor-acceptor (EDA) complexes have recently emerged as a powerful and sustainable alternative to iridium- and ruthenium-based photoredox synthetic methods. Yet, these complexes remain underexplored and reliant on the use of meticulously designed acceptors… read more here.
Keywords: general platform; visible light; eda complexes; sulfonylation ... See more keywords