Edge-Sharing Octahedrally Coordinated NiFe Dual Active Sites on ZnFe2 O4 for Photoelectrochemical Water Oxidation.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced science"
DOI: 10.1002/advs.202301869
Abstract: The structural properties of octahedral sites (BOh ) in spinel oxides (AB2 O4 ) play vital roles in the electrochemical performance of oxygen-related reactions. However, the precise manipulation of AB2 O4 remains challenging due to… read more here.
Keywords: active sites; dual active; edge sharing; water oxidation ... See more keywords
Electron transfer calculations between edge sharing octahedra in hematite, goethite, and annite
Sign Up to like & getrecommendations! Published in 2020 at "Geochimica et Cosmochimica Acta"
DOI: 10.1016/j.gca.2020.04.036
Abstract: Abstract A key reaction underlying the charge transport in iron containing oxides, clays, micas is the Fe 2 + - Fe 3 + exchange reaction between edge-sharing iron octahedra. These reactions facilitate conduction in these… read more here.
Keywords: hematite goethite; polaron; edge sharing; electron transfer ... See more keywords
γ-BaB2O4: High-Pressure High-Temperature Polymorph of Barium Borate with Edge-Sharing BO4 Tetrahedra.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03760
Abstract: The α- and β-modifications of barium metaborate are important functional materials used in optoelectronic devices. A new theoretically predicted modification of BaB2O4 has been synthesized under conditions of 3 GPa and 900 °C, using the… read more here.
Keywords: high pressure; bab2o4; edge sharing; bab2o4 high ... See more keywords
CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c04026
Abstract: SO4 tetrahedral groups have weak polarization anisotropy, which thus results in the small birefringence of sulfates. Here, we report new sulfate CsY(SO4)2·4H2O with unprecedented birefringence among deep-ultraviolet (deep-UV) sulfates. Its single crystal (10 mm ×… read more here.
Keywords: edge sharing; so4 4h2o; birefringence; deep ultraviolet ... See more keywords
LiMo8O10: Polar Crystal Structure with Infinite Edge-Sharing Molybdenum Octahedra.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01917
Abstract: Polycrystalline LiMo8O10 was prepared in a sealed Mo crucible at 1380 °C for 48 h using the conventional high-temperature solid-state method. The polar tetragonal crystal structure (space group I41md) is confirmed based on the Rietveld… read more here.
Keywords: edge sharing; limo8o10; crystal structure; edge ... See more keywords
C10H6NO2Cd(NO3)·2H2O: a birefringent crystal with an enlarged band-gap derived from covalent edge-sharing connection.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00688c
Abstract: A new birefringent crystal, C10H6NO2Cd(NO3)·2H2O, was designed by combining a π-conjugated [C10H6NO2]- group with a CdO7N polyhedron. Notably, the experimental energy gap is 0.02 eV higher than that of the organic raw material, which resulted… read more here.
Keywords: no3 2h2o; edge sharing; c10h6no2cd no3; covalent edge ... See more keywords