Triiron clusters derived from dinuclear complexes related to the active site of [Fe–Fe] hydrogenases: steric effect of the dithiolate bridge on redox properties, a DFT analysis
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DOI: 10.1039/d1qi00006c
Abstract: A series of triiron clusters [Fe3(CO)5(κ2-dppe)(μ-pdtR2)(μ-pdt)] featuring different combinations of dithiolate bridges have been prepared by using dinuclear and mononuclear precursors, [Fe2(CO)6(μ-xdt)] (xdt = pdt, pdtEt2, pdtBn2, adtBn) and [Fe(CO)2(κ2-dppe)(κ2-pdt)]. Novel triiron compounds, featuring sterically… read more here.
Keywords: redox; effect dithiolate; dithiolate; triiron clusters ... See more keywords