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Published in 2018 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2018.01.001
Abstract: An accurate and efficient prediction of the NMR spectra of organoelement compounds containing heavy elements is on the cutting edge of the modern chemistry. Reviewed herewith are the relativistic effects provided by heavy chalcogens on…
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Keywords:
effects nmr;
relativistic effects;
nmr spectra;
heavy chalcogens ... See more keywords
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2
Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01996
Abstract: A wide range of functionalized pyridine ligands have been employed to synthesize a variety of Pd(II) complexes of the general formulas [PdL4](NO3)2 and [PdL2Y2], where L = 4-X-py and Y = Cl– or NO3–. Their…
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Keywords:
ligands substituent;
effects nmr;
chemistry;
complexes pyridine ... See more keywords
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Published in 2019 at "Molecules"
DOI: 10.3390/molecules24234399
Abstract: Relativistic effects are found to be important for the estimation of NMR parameters in halogen-bonded complexes, mainly when they involve the heavier elements, iodine and astatine. A detailed study of 60 binary complexes formed between…
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Keywords:
bonded complexes;
halogen bonded;
effects nmr;
relativistic effects ... See more keywords