Steric and Solvation Effects on Polymerization Kinetics, Dormancy, and Tacticity of Zr-Salan Catalysts
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DOI: 10.1021/acs.organomet.7b00295
Abstract: 1-Hexene polymerization using four zirconium-based amine bis(phenolate) catalysts, Zr[2-R-4-tBu-ONNO]Bn2 (where R = methyl (1), ethyl (2), isopropyl (3), and tert-butyl (4)), was examined to establish the effect of ligand sterics on kinetics and stereocontrol of… read more here.
Keywords: polymerization; polymerization kinetics; dormancy; steric solvation ... See more keywords