Efficient Copper‐Free Sonogashira Coupling in Water and under Ambient Atmosphere
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DOI: 10.1002/ejoc.202400223
Abstract: Sonogashira coupling is one of the cornerstone Palladium mediated cross coupling reactions, giving a direct and high yield access to symmetric and non‐symmetric alkynes with high tolerance of substituents. The method generally requires the use… read more here.
Keywords: sonogashira; efficient copper; sonogashira coupling; coupling water ... See more keywords
An Efficient Copper-Catalyzed C(sp2)–S Formation Starting from Aryl Iodides and Tetramethylthiuram Monosulfide (TMTM)
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DOI: 10.1055/s-0040-1707899
Abstract: A new, efficient copper-catalyzed C(sp2)–S formation of phenyl dithiocarbamates starting from aryl iodides and tetramethylthiuram monosulfide (TMTM) was developed. The target compounds, phenyl dithiocarbamates with active sites, were synthesized smoothly in good to excellent yields.… read more here.
Keywords: catalyzed sp2; formation; starting aryl; sp2 formation ... See more keywords