Potassium isopropyl xanthate (PIX): an ultra-efficient palladium scavenger
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DOI: 10.1039/c7gc01765k
Abstract: The increasing employment of palladium-catalyzed reactions in the synthesis of active pharmaceutical ingredients (APIs) has created a pressing need for ultra-efficient palladium removal of the resulting metal contaminants. This communication discusses the identification and development… read more here.
Keywords: ultra efficient; chemistry; efficient palladium; palladium ... See more keywords
An Efficient Palladium-Catalyzed α-Arylation of Acetone Below its Boiling Point
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DOI: 10.1055/s-0040-1706409
Abstract: The monoarylation of acetone is a powerful transformation, but is typically performed at temperatures significantly in excess of its boiling point. Conditions described for performing the reaction at ambient temperatures led to significant dehalogenation when… read more here.
Keywords: acetone; boiling point; palladium catalyzed; efficient palladium ... See more keywords