Metal-carbene unit: a universal tool towards high-efficient photochemical reaction in solution
Sign Up to like & getrecommendations! Published in 2019 at "Science China Chemistry"
DOI: 10.1007/s11426-019-9459-3
Abstract: Topochemically-controlled stereoselective [2+2] photocycloadditions are now well-established in the literatures. The construction of cyclobutane rings has attracted considerable attention due to the existence of this structural motif in natural products and synthetic medicines. Furthermore, cyclobutane… read more here.
Keywords: solid state; metal carbene; control; solution ... See more keywords
Highly Efficient Photochemical Vapor Generation for Sensitive Determination of Iridium by Inductively Coupled Plasma Mass Spectrometry
Sign Up to like & getrecommendations! Published in 2023 at "Analytical Chemistry"
DOI: 10.1021/acs.analchem.2c04660
Abstract: Herein, we describe the highly efficient photochemical vapor generation (PVG) of a volatile species of Ir (presumably iridium tetracarbonyl hydride) for subsequent detection by inductively coupled plasma mass spectrometry (ICPMS). A thin-film flow-through photoreactor, operated… read more here.
Keywords: photochemical vapor; coupled plasma; highly efficient; efficient photochemical ... See more keywords
Efficient Photochemical Vapor Generation of Molybdenum for ICPMS Detection.
Sign Up to like & getrecommendations! Published in 2018 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.8b03354
Abstract: Photochemical vapor generation (PVG) of Mo was accomplished using a 19 W high-efficiency flow-through photoreactor operating in a flow injection mode using 30-50% (w/v) formic acid as a reaction medium. The generated volatile product (most… read more here.
Keywords: efficient photochemical; detection; vapor generation; photochemical vapor ... See more keywords