Hydride-Containing Eight-Electron Pt/Ag Superatoms: Structure, Bonding, and Multi-NMR Studies.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c03715
Abstract: Recent reports on hydride-doped noble metal nanoclusters strongly suggest that the encapsulated hydride is a part of the superatom core, but no accurate location of the hydride could be experimentally proved, so far. We report… read more here.
Keywords: multi nmr; structure; hydride; electron ... See more keywords
The stability enhancement factor beyond eight-electron shell closure in thiacalix[4]arene-protected silver clusters
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c8sc03756f
Abstract: Destroying coordination open sites may significantly enhance the stability of metal nanoclusters. read more here.
Keywords: beyond eight; factor beyond; eight electron; electron shell ... See more keywords
All-selenolate-protected eight-electron platinum/silver nanoclusters.
Sign Up to like & getrecommendations! Published in 2021 at "Nanoscale"
DOI: 10.1039/d1nr02540f
Abstract: The first atomically and structurally precise platinum/silver superatoms protected by Se-donor ligands were synthesized in high yield by adopting ligand replacements on [PtAg20{S2P(OnPr)2}12] (3) with 12 equiv. of di-alkyl diselenophosph(in)ates. Structures of [PtAg20{Se2P(OR)2}12] (R =… read more here.
Keywords: platinum silver; protected eight; eight electron; silver ... See more keywords