Eightfold Electrophilic Methylation of Octacyanotungstate [W(CN)8]4-/3-: Preparation of Homoleptic, Eight-Coordinate Methyl Isocyanide Complexes [W(CNMe)8]4+/5.
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DOI: 10.1021/acs.inorgchem.1c00326
Abstract: Homoleptic eightfold coordinated methyl isocyanide complexes of W(IV) and W(V) have been prepared for the first time. The reaction of [NBu4]4[W(CN)8] with methyl triflate (MeOTf) gives [W(CNMe)8][OTf]4. The even stronger methylating mixture of methyl fluoride… read more here.
Keywords: isocyanide complexes; octacyanotungstate preparation; methylation octacyanotungstate; eightfold electrophilic ... See more keywords