Tuning the Reactivity of TEMPO during Electrocatalytic Alcohol Oxidations in Room-Temperature Ionic Liquids
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.9b01823
Abstract: 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) is a promising, sustainable, metal-free mediator for oxidation of alcohols. In this contribution, we describe how the selectivity of TEMPO for electroca... read more here.
Keywords: tuning reactivity; reactivity tempo; tempo; electrocatalytic alcohol ... See more keywords
Electrocatalytic alcohol oxidation by a molecular iron complex.
Sign Up to like & getrecommendations! Published in 2022 at "Faraday discussions"
DOI: 10.1039/d1fd00074h
Abstract: An efficient electrochemical method for the selective oxidation of alcohols to their corresponding aldehydes/ketones using a biomimetic iron complex, [(bTAML)FeIII-OH2]-, as the redox mediator in an undivided electrochemical cell with inexpensive carbon and nickel electrodes… read more here.
Keywords: reaction; electrocatalytic alcohol; oxidation; iron complex ... See more keywords