Electrode Materials Engineering in Electrocatalytic CO2 Reduction: Energy Input and Conversion Efficiency.
Sign Up to like & getrecommendations! Published in 2019 at "Advanced materials"
DOI: 10.1002/adma.201903796
Abstract: Electrocatalytic CO2 reduction (ECR) is a promising technology to simultaneously alleviate CO2 -caused climate hazards and ever-increasing energy demands, as it can utilize CO2 in the atmosphere to provide the required feedstocks for industrial production… read more here.
Keywords: co2 reduction; ecr systems; energy; conversion ... See more keywords
Partially Nitrided Ni Nanoclusters Achieve Energy‐Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202205262
Abstract: Electrocatalytic CO2 reduction reaction (CO2RR) offers a promising strategy to lower CO2 emission while producing value‐added chemicals. A great challenge facing CO2RR is how to improve energy efficiency by reducing overpotentials. Herein, partially nitrided Ni… read more here.
Keywords: partially nitrided; electrocatalytic co2; energy; nitrided nanoclusters ... See more keywords
Alloy Catalysts for Electrocatalytic CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2023 at "Small methods"
DOI: 10.1002/smtd.202300482
Abstract: CO2 conversion is an anticipated route to resolve the energy crisis and environmental pollution, in which electrocatalysis is one of the technologies closest to industrialization. Alloy catalysts are promising candidates for electrocatalysis, and the high… read more here.
Keywords: electrocatalytic co2; catalysts electrocatalytic; co2 reduction; alloy catalysts ... See more keywords
A computational study of electrocatalytic CO2 reduction by Mn(I) complexes: Role of bipyridine substituents
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.11.210
Abstract: Abstract Using density functional theory (DFT), a series of Mn(4,4′-R-bpy)(CO)3Br (bpy = 2,2′-bipyridine, R = CN, CF3, COOH, H, CH3, tBu, and OCH3) complexes has been studied for electrocatalytic CO2 to CO reduction. Here, we show that the formation… read more here.
Keywords: co2 reduction; electron withdrawing; electrocatalytic co2; reduction ... See more keywords
Electrocatalytic CO2 Reduction by Self-Assembled Monolayers of Metal Porphyrins
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c06397
Abstract: The main issue hindering the successful utilization of CO2 electroreduction processes in industry is the lack of selective, durable, and efficient catalysts. In this work, a new heterogeneous molec... read more here.
Keywords: co2 reduction; assembled monolayers; self assembled; co2 ... See more keywords
Nanocapillarity and Nanoconfinement Effects of Pipet-like Bismuth@Carbon Nanotubes for Highly Efficient Electrocatalytic CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2021 at "Nano letters"
DOI: 10.1021/acs.nanolett.1c00390
Abstract: Electrocatalytic CO2 reduction reaction is regarded as an intriguing route for producing renewable chemicals and fuels, but its development is limited by the lack of highly efficient and stable electrocatalysts. Herein, we propose the pipet-like… read more here.
Keywords: highly efficient; co2 reduction; co2; electrocatalytic co2 ... See more keywords
Bi2O3/BiO2 Nanoheterojunction for Highly Efficient Electrocatalytic CO2 Reduction to Formate.
Sign Up to like & getrecommendations! Published in 2022 at "Nano letters"
DOI: 10.1021/acs.nanolett.1c04683
Abstract: Heterostructure engineering plays a vital role in regulating the material interface, thus boosting the electron transportation pathway in advanced catalysis. Herein, a novel Bi2O3/BiO2 heterojunction catalyst was synthesized via a molten alkali-assisted dealumination strategy and… read more here.
Keywords: electrocatalytic co2; co2 reduction; bi2o3 bio2;
Synergistic Metal–Ligand Redox Cooperativity for Electrocatalytic CO2 Reduction Promoted by a Ligand-Based Redox Couple in Mn and Re Tricarbonyl Complexes
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00584
Abstract: Electrocatalytic CO2 reduction is demonstrated for the Mn and Re tricarbonyl complexes, [M(Me2OQN)(CO)3(CH3CN)] (M = Mn or Re) containing the 5,7-dimethyl-8-oxyquinolate (Me2OQN–) ligand. In comparison to the related 2,2′-bipyridyl (bpy) reference complexes, [M(bpy)(CO)3(CH3CN)]+ (M =… read more here.
Keywords: redox couple; co2 reduction; electrocatalytic co2; tricarbonyl complexes ... See more keywords
Low-Energy Electrocatalytic CO2 Reduction in Water over Mn-Complex Catalyst Electrode Aided by a Nanocarbon Support and K+ Cations
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01068
Abstract: Electrocatalytic CO2 reduction over a Mn-complex catalyst in an aqueous solution was achieved at very low energy with a combination of multiwalled carbon nanotubes (MWCNTs) and K+ cations. Although the bare Mn-complex did not function… read more here.
Keywords: co2; co2 reduction; electrocatalytic co2; complex catalyst ... See more keywords
Boosting Defective Carbon by Anchoring Well-Defined Atomically Dispersed Ni–N4 Sites for Electrocatalytic CO2 Reduction
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c03222
Abstract: To enhance the faradic efficiency of the electrocatalytic CO2 reduction reaction (CO2RR) with stable catalysts, atomically dispersed Ni–N5 active sites composed of planar Ni–N4 (in nickel phthalocy... read more here.
Keywords: defective carbon; co2 reduction; atomically dispersed; boosting defective ... See more keywords
Lowering Electrocatalytic CO2 Reduction Overpotential Using N-Annulated Perylene Diimide Rhenium Bipyridine Dyads with Variable Tether Length.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c09481
Abstract: We report the design, synthesis, and characterization of four N-annulated perylene diimide (NPDI) functionalized rhenium bipyridine [Re(bpy)] supramolecular dyads. The Re(bpy) scaffold was connected to the NPDI chromophore either directly [Re(py-C0-NPDI)] or via an ethyl… read more here.
Keywords: bpy npdi; electrocatalytic co2; co2 reduction; bpy ... See more keywords