Conjugated Cobalt Porphyrin Polymer for Highly Active and Selective Electrocatalytic Nitrite Reduction to Ammonia
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DOI: 10.1002/adfm.202424566
Abstract: Electrocatalytic nitrite (NO2−) reduction (NO2RR) to ammonia (NH3) is a promising green technology for producing NH3 with high efficiency. Cobalt macrocyclic complexes have attracted great interest because of their ability to selectively convert NO2− to… read more here.
Keywords: cobalt porphyrin; electrocatalytic nitrite; ammonia; conjugated cobalt ... See more keywords
Electrocatalytic Nitrite Reduction With Polynuclear Copper(I) Complexes Supported By 2‐Mercaptopyridine Ligand
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DOI: 10.1002/cctc.202500374
Abstract: The electrochemical nitrite reduction to ammonia is a growing interest in chemistry as it can be a potential alternative to the energy‐intensive Haber–Bosch. In this work, two copper complexes supported by pyridine‐2‐thiol (PySH), [CuI6(PyS)6] (1),… read more here.
Keywords: copper complexes; complexes supported; copper; electrocatalytic nitrite ... See more keywords
Electrocatalytic Nitrite Reduction by a Monomeric NrfA: Commonality in Ammonification Mechanisms.
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DOI: 10.1021/acs.biochem.4c00761
Abstract: Cytochrome c nitrite reductase (NrfA) is a pentaheme enzyme capable of the six-electron reduction of nitrite to ammonia, which is a key step in the nitrogen cycle. All NrfA enzymes appear to have a branched… read more here.
Keywords: reduction monomeric; monomeric nrfa; electrochemistry; electrocatalytic nitrite ... See more keywords