Molybdenum Carbide Nanodots Enable Efficient Electrocatalytic Nitrogen Fixation under Ambient Conditions.
Sign Up to like & getrecommendations! Published in 2018 at "Advanced materials"
DOI: 10.1002/adma.201803694
Abstract: Electrocatalytic nitrogen fixation is considered a promising approach to achieve NH3 production. However, due to the chemical inertness of nitrogen, it is necessary to develop efficient catalysts to facilitate the process of nitrogen reduction. Here,… read more here.
Keywords: nitrogen; electrocatalytic nitrogen; nitrogen fixation; carbide nanodots ... See more keywords
Modulating the Active Sites of Oxygen-Deficient TiO2 by Copper Loading for Enhanced Electrocatalytic Nitrogen Reduction to Ammonia.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202200996
Abstract: The electrocatalytic nitrogen reduction reaction (NRR) provides a sustainable route for NH3 synthesis. However, the process is plagued by the strong NN triple bond and high reaction barrier. Modification of catalyst surface to increase N2… read more here.
Keywords: oxygen deficient; electrocatalytic nitrogen; deficient tio2; nitrogen reduction ... See more keywords
Vanadium carbide with periodic anionic vacancies for effective electrocatalytic nitrogen reduction
Sign Up to like & getrecommendations! Published in 2020 at "Materials Today"
DOI: 10.1016/j.mattod.2020.04.031
Abstract: Abstract Although electrocatalytic nitrogen reduction reaction (NRR) has been considered as an emerging pathway to produce ammonia (NH3) under ambient conditions owing to its low energy consumption, it still lacks efficient the electrocatalysts to dissociate… read more here.
Keywords: electrocatalytic nitrogen; vanadium; vanadium carbide; reduction ... See more keywords
Simple Bottom-Up Synthesis of Bismuthene Nanostructures with a Suitable Morphology for Competitive Performance in the Electrocatalytic Nitrogen Reduction Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03938
Abstract: Nitrogen reduction to ammonia under ambient conditions has received important attention, in which high-performing catalysts are sought. A new, facile, and seedless solvothermal method based on a high-temperature reduction route has been developed in this… read more here.
Keywords: performance electrocatalytic; reaction; nitrogen reduction; bismuthene nanostructures ... See more keywords
Multicomponent TiO2/Ag/Cu7S4@Se Heterostructures Constructed by an Interface Engineering Strategy for Promoting the Electrocatalytic Nitrogen Reduction Reaction Performance.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00720
Abstract: The electrocatalytic nitrogen reduction reaction (ECNRR) is a sustainable and environmentally friendly method for NH3 synthesis under environmental conditions relative to the Haber-Bosch process; however, its low selectivity (Faradaic efficiency (FE)) and low NH3 yield… read more here.
Keywords: electrocatalytic nitrogen; nitrogen reduction; reduction reaction; tio2 ... See more keywords
Breaking the Volcano-Shaped Relationship for Highly Efficient Electrocatalytic Nitrogen Reduction: A Computational Guideline.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c14134
Abstract: The volcano-shaped relationship is very common in electrocatalytic nitrogen reduction reaction (e-NRR) and is usually caused by the competition between the first and last hydrogenation steps. How to break such a relationship to further improve… read more here.
Keywords: volcano shaped; electrocatalytic nitrogen; relationship; nitrogen reduction ... See more keywords
Mo2C-MoO2 Heterostructure Quantum Dots for Enhanced Electrocatalytic Nitrogen Reduction to Ammonia.
Sign Up to like & getrecommendations! Published in 2021 at "ACS nano"
DOI: 10.1021/acsnano.1c07973
Abstract: The electrocatalytic nitrogen reduction reaction (NRR) has been regarded as a promising strategy for producing ammonia (NH3) at ambient conditions. However, the development of the NRR is severely hindered by the difficult adsorption and activation… read more here.
Keywords: nitrogen reduction; moo2; mo2c moo2; electrocatalytic nitrogen ... See more keywords
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Society reviews"
DOI: 10.1039/c9cs00280d
Abstract: The efficient activation of dinitrogen for the production of ammonia plays a crucial role in our modern society, considering the significant impact of ammonia on food, chemicals, and energy. As an attractive alternative to the… read more here.
Keywords: nitrogen; electrocatalytic nitrogen; nitrogen reduction; explore ambient ... See more keywords
Ni nanoparticles/V4C3Tx MXene heterostructures for electrocatalytic nitrogen fixation
Sign Up to like & getrecommendations! Published in 2021 at "Materials Chemistry Frontiers"
DOI: 10.1039/d0qm00898b
Abstract: Reported here is a nanocomposite consisting of Ni nanoparticles loaded on V4C3Tx MXene as a highly efficient NRR electrocatalyst. The critical role of V4C3Tx MXene in suppressing the HER activity and enhancing the NRR performance… read more here.
Keywords: heterostructures electrocatalytic; v4c3tx mxene; mxene heterostructures; electrocatalytic nitrogen ... See more keywords
Free radicals promote electrocatalytic nitrogen oxidation
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d2sc06599a
Abstract: In this work, we introduce hydroxyl radicals into the electrocatalytic nitrogen oxidation reaction (NOR) for the first time. Cobalt tetroxide (Co3O4) acts not only as an electrocatalyst, but also as a nanozyme (in combination with… read more here.
Keywords: nitrogen oxidation; electrocatalytic nitrogen; free radicals; co3o4 ... See more keywords
Advancing electrocatalytic nitrogen fixation: insights from molecular systems.
Sign Up to like & getrecommendations! Published in 2023 at "Faraday discussions"
DOI: 10.1039/d3fd00017f
Abstract: Nitrogen fixation has a rich history within the inorganic chemistry community. In recent years attention has (re)focused on developing electrocatalytic systems capable of mediating the nitrogen reduction reaction (N2RR). Well-defined molecular catalyst systems have much… read more here.
Keywords: electrocatalytic nitrogen; advancing electrocatalytic; fixation insights; nitrogen ... See more keywords