Reversible isomerization of a novel [FeFe]‑hydrogenase model complex and water-promoted electrocatalytic proton reduction
Sign Up to like & getrecommendations! Published in 2017 at "Electrochemistry Communications"
DOI: 10.1016/j.elecom.2017.07.025
Abstract: Abstract μ-(SCH(CH 2 CH 3 )CH 2 S)-Fe 2 (CO) 4 (κ 2 -DPPE) (complex 1, DPPE is 1,2-bis (diphenylphosphor) ethane), which can be regarded as a model of the [FeFe]‑hydrogenase active site, was synthesized… read more here.
Keywords: proton reduction; reversible isomerization; electrocatalytic proton; fefe hydrogenase ... See more keywords
Redox-Induced Structural Switching through Sporadic Pyridine-Bridged CoIICoII Dimer and Electrocatalytic Proton Reduction.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00911
Abstract: The homodinuclear CoII helicate complex [CoII(DQPD)]2 (1) was prepared by treating [Co(H2O)6](ClO4)2 with the deprotonated form of the ligand N2,N6-bis(quinolin-8-yl)pyridine-2,6-dicarboxamide (DQPDH2). Complex 1 represents a discrete homodinuclear helicate complex with two CoII centers having a… read more here.
Keywords: pyridine; proton reduction; electrocatalytic proton; proton ... See more keywords
Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02505
Abstract: Cobalt complexes with 2-(diisopropylphosphinomethyl)pyridine (PN) ligands have been synthesized with the aim of demonstrating electrocatalytic proton reduction to dihydrogen with a well-defined hydride complex of an Earth-abundant metal. Reactions of simple cobalt precursors with 2-(diisopropylphosphino-methyl)pyridine… read more here.
Keywords: cobalt; proton reduction; electrocatalytic proton; proton ... See more keywords
Efficient Electrocatalytic Proton Reduction with Carbon Nanotube-Supported Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b09521
Abstract: Hydrogen production from Earth-abundant catalysts remains an important but difficult challenge. Here we report the growth of Hf12-porphyrin metal-organic frameworks (MOFs) on carbon nanotubes (CNTs) for electrocatalytic proton reduction. Covalent attachment of MOF nanoplates to… read more here.
Keywords: proton reduction; metal organic; electrocatalytic proton; proton ... See more keywords