Electrochemical Benzylic C(sp3)–H Acyloxylation
Sign Up to like & getrecommendations! Published in 2022 at "Organic Letters"
DOI: 10.1021/acs.orglett.2c01930
Abstract: The development of sustainable C(sp3)–H functionalization methods is of great interest to the pharmaceutical and agrochemical industries. Anodic oxidation is an efficient means of producing benzylic cations that can undergo subsequent in situ nucleophilic attack… read more here.
Keywords: benzylic sp3; sp3 acyloxylation; sp3; electrochemical benzylic ... See more keywords
Electrochemical benzylic oxidation of C-H bonds.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc08768g
Abstract: Oxidized products have become increasingly valuable as building blocks for a wide variety of different processes and fine chemistry, especially in the benzylic position. We report herein a sustainable protocol for this transformation through C-H… read more here.
Keywords: electrochemical benzylic; chemistry; benzylic oxidation; oxidation bonds ... See more keywords