Revisiting the Electrochemical Carboxylation of Naphthalene with CO2: Selective Monocarboxylation of 2-Substituted Naphthalenes.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01033
Abstract: Numerous remarkable reactions based on electrochemical carboxylations using CO2 have recently attracted considerable attention. In contrast to more recent examples, the electrochemical carboxylation of naphthalene had already been established in 1959, whereby a dearomative dicarboxylation… read more here.
Keywords: revisiting electrochemical; electrochemical carboxylation; carboxylation naphthalene; naphthalene co2 ... See more keywords
Direct Electrochemical Carboxylation of Benzylic C–N Bonds with Carbon Dioxide
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b00818
Abstract: We report a direct and efficient electrochemical carboxylation of benzylic C–N bonds with CO2 at room temperature. The reaction has been successfully applied to both primary and secondary benzylic C–N bonds with the compatibility of… read more here.
Keywords: electrochemical carboxylation; carboxylation benzylic; direct electrochemical; benzylic bonds ... See more keywords
Green synthesis of α-amino acids by electrochemical carboxylation of imines in a flow microreactor
Sign Up to like & getrecommendations! Published in 2017 at "Reaction Chemistry and Engineering"
DOI: 10.1039/c7re00149e
Abstract: A new approach for the green synthesis of α-amino acids using electrochemical carboxylation of imines in a flow microreactor is described. This method has the major advantage of not requiring sensitive, expensive, or toxic reagents.… read more here.
Keywords: amino acids; electrochemical carboxylation; green synthesis; synthesis amino ... See more keywords
Distinguishing the mechanism of electrochemical carboxylation in CO2 eXpanded Electrolytes.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06560f
Abstract: We shed light on the mechanism and rate-determining steps of the electrochemical carboxylation of acetophenone as a function of CO2 concentration by using a robust finite element analysis model that incorporates each reaction step. Specifically,… read more here.
Keywords: distinguishing mechanism; co2; electrochemical carboxylation; acetophenone ... See more keywords