Electrochemical Cobalt-Catalyzed C-H Oxygenation at Room Temperature.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11025
Abstract: Electrochemical cobalt-catalyzed C-H functionalizations were achieved in terms of C-H oxygenation under mild conditions at 23 °C. The robust electrochemical C-H functionalization was characterized by ample substrate scope, whereas mechanistic studies provided support for a… read more here.
Keywords: electrochemical cobalt; oxygenation room; catalyzed oxygenation; cobalt catalyzed ... See more keywords
Carboxylate breaks the arene C–H bond via a hydrogen-atom-transfer mechanism in electrochemical cobalt catalysis†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc01898h
Abstract: Combined computational and experimental studies elucidated the distinctive mechanistic features of electrochemical cobalt-catalyzed C–H oxygenation. A sequential electrochemical–chemical (EC) process was identified for the formation of an amidylcobalt(iii) intermediate. The synthesis, characterization, cyclic voltammetry studies,… read more here.
Keywords: carboxylate; electrochemical cobalt; cobalt; mechanism ... See more keywords