Electrochemical Flux Synthesis of Type-I Na8Si46 Clathrates: Particle Size Control Using a Solid or Molten Na-Sn Mass Transport Mediator.
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DOI: 10.1021/acs.inorgchem.2c03811
Abstract: Sodium-filled silicon clathrates have a host of interesting properties for thermoelectric, photovoltaic, and battery applications. However, the metastability of the clathrates has made it difficult to synthesize them with the desired morphology and crystallite size.… read more here.
Keywords: type na8si46; electrochemical flux; synthesis type; type ... See more keywords