Selective Electrochemical Oxygenation of Alkylarenes to Carbonyls.
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DOI: 10.1021/acs.orglett.1c02651
Abstract: An efficient electrochemical method for benzylic C(sp3)-H bond oxidation has been developed. A variety of methylarenes, methylheteroarenes, and benzylic (hetero)methylenes could be converted into the desired aryl aldehydes and aryl ketones in moderate to excellent… read more here.
Keywords: electrochemical oxygenation; oxygenation alkylarenes; alkylarenes carbonyls; selective electrochemical ... See more keywords
Aerobic Electrochemical Oxygenation of Light Hydrocarbons Catalyzed by an Iron–Tungsten Oxide Molecular Capsule
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b00477
Abstract: The selective oxidation of light hydrocarbons and their valorization with only dioxygen (O2) are important transformations toward development of efficient chemical processes. Monooxygenase enzymes can catalyze selective aerobic reactions under reducing and protic conditions. The… read more here.
Keywords: electrochemical oxygenation; oxygenation light; light hydrocarbons; aerobic electrochemical ... See more keywords