Electrochemical-Promoted Nickel-Catalyzed Oxidative Fluoroalkylation of Aryl Iodides.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02997
Abstract: This work describes a general strategy for metal-catalyzed cross-coupling of fluoroalkyl radicals with aryl halides under electrochemical conditions. The contradiction between anodic oxidation of fluoroalkyl sulfinates and cathodic reduction of low-valent nickel catalysts can be… read more here.
Keywords: oxidative fluoroalkylation; fluoroalkylation aryl; electrochemical promoted; promoted nickel ... See more keywords
Electrochemical Mn-Promoted Radical Selenylation of Boronic Acids with Diselenide Reagents.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00607
Abstract: A powerful and environmentally friendly electrochemical manganese-promoted free radical selenylation reaction between boronic acids and diselenide reagents was established. This electrochemical protocol provides a practically applicable way to a series of valuable organoselenium compounds with… read more here.
Keywords: boronic acids; acids diselenide; electrochemical promoted; diselenide reagents ... See more keywords
Electrochemical-Promoted Homocoupling of 2'-Hydroxychalcones for the Synthesis of 1,6-Diketones.
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DOI: 10.1021/acs.orglett.5c01840
Abstract: 1,6-Dicarbonyl compounds are versatile building blocks for the construction of pharmaceutically and biologically active heterocycles and carbocycles; yet, their efficient synthesis remains a challenge. Herein, a straightforward and efficient route for the synthesis of 1,6-diketones… read more here.
Keywords: hydroxychalcones synthesis; synthesis diketones; synthesis; electrochemical promoted ... See more keywords