Synthesis, Characterization and Electrochemical Reductive Properties of Complexes [Fe 2 (CO) 4 (κ 2 ‐P Ph 2 N R 2 )( µ ‐dithiolato)] Related to the H‐Cluster of [FeFe]‐H 2 ases
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DOI: 10.1002/ejic.202000824
Abstract: A series of dithiolate carbonyl diiron complexes with cyclic azadiphosphine, related to the active site of [FeFe]‐hydrogenases, has been prepared. Several combinations of diphosphines and dithiolate bridges have been examined in order to obtain information… read more here.
Keywords: synthesis characterization; properties complexes; characterization electrochemical; reductive properties ... See more keywords
Electrochemical Reductive Smiles Rearrangement for C-N Bond Formation.
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DOI: 10.1021/acs.orglett.8b03178
Abstract: A conceptually new and synthetically valuable radical Smiles rearrangement reaction is reported under undivided electrolytic conditions. This protocol employs an entirely new strategy for the electrochemical radical Smiles rearrangement. Remarkably, an amidyl radical generated from… read more here.
Keywords: rearrangement bond; bond formation; bond; electrochemical reductive ... See more keywords